Natural Sciences and their Technologies
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Pregunta de Natural Sciences and their Technologies #019e354b

Enunciado de la Pregunta
Natural Sciences and their Technologies
#química
#química ambiental
#poluição atmosférica
#combustão
#natureza
Medio

Um dos agentes que mais contribui para a poluição do ar é o automóvel a combustão interna. Em áreas urbanas, isso é demonstrado dramaticamente pela fumaça fotoquímica, resultante da interação entre óxidos de nitrogênio, hidrocarbonetos e luz solar, para formar produtos de oxidação, que causam irritação aos olhos, ao aparelho respiratório e danos às plantas. As condições de operação de motores a combustão, como a razão da mistura ar/combustível no cilindro, influenciam na composição dos gases lançados pelo escapamento na atmosfera. O gráfico ilustra a variação nas composições dos principais gases, dióxido de carbono (), hidrocarbonetos (), monóxido de carbono (), monóxido de nitrogênio () e oxigênio molecular (), emitidos por um motor a gasolina, em diferentes razões ar/combustível, em massa.

Content Image
RANGEL, MC; CARVALHO, MFA. Impact of automotive catalysts on air quality control. Química Nova, v. 26,

Under conditions of an air/fuel ratio equal to 18, there will be an emission

A

Low O2 and high NO.

B

Low NO and high HC.

C

Low CO2 levels and high CO2 levels.

Correcto
D

Low HC and high CO.

E

Low CO2 and high HC.

Explicación Oficial / Explicaciones de la Comunidad

Analysis of Combustion Engine Gas Emissions

The correct answer is option A. C) Low CO and high CO₂.


1. Problem-solving strategy: Reading the graph

The question asks to analyze the emissions of different gases under a specific condition: a air/fuel ratio equal to 18To solve this, simply locate this value on the horizontal axis (X-axis) of the graph and observe the levels of the corresponding curves at that point.

2. Analysis at Air/Fuel Ratio = 18

  1. Locate the Point: Find the number 18 on the X-axis ("Air/Fuel Ratio"). 2. Draw a vertical line: Imagine or draw a vertical line upwards from point 18. 3. Observe the intersections: See where this vertical line intersects each of the colored curves that represent the gases.

Let's analyze the gases mentioned in the options at this specific point:

  • CO (Carbon Monoxide - green curve): Upon reaching a ratio of 18, the green CO2 curve has already plummeted and is at its minimum level, very close to zero. Therefore, the emission of CO is low.

  • CO₂ (Carbon Dioxide - blue curve): At a ratio of 18, the blue CO₂ curve is at a high level, around 12% by volume. Although it has passed its peak (which occurs near the stoichiometric ratio), it is still a very high value compared to other pollutants. Therefore, the emission of CO₂ is high.

  • HC (Hydrocarbons - red curve): The red curve of HC is at one of its lowest points at a ratio of 18. Therefore, the emission of HC is low.

  • NO (Nitrogen Monoxide - orange curve): The orange curve for NO has already passed its peak (which occurs around 16) and is declining. Therefore, its emission is moderate, but not high.

  • O₂ (Molecular Oxygen - light blue curve): The O₂ curve is rising, indicating a moderate level of unconsumed oxygen, as there is excess air in the mixture.

3. Evaluation of Alternatives

Based on the previous analysis, let's examine the options:

  • A) Low O₂ and high NO: Incorrect. Oxygen emissions are moderate/high, and NO emissions are declining. * B) Low NO and high HC: Incorrect. HC emissions are low. * C) Low CO₂ and high CO₂: Correct. CO emissions are very low, while CO₂ emissions are high. * D) Low HCl and high CO2: Incorrect. CO2 emissions are low. * E) Low CO₂ and high HC: Incorrect. CO₂ emissions are high and HC emissions are low.

4. Conclusion

A direct reading of the graph at the point corresponding to an air/fuel ratio of 18 unequivocally shows very low emissions of carbon monoxide (CO) and high emissions of carbon dioxide (CO₂).